Air stable NHCs: a study of stereoelectronics and metallorganic catalytic activity.
نویسندگان
چکیده
The air stable NHC IPrBr is reported. A stereoelectronic study of IPrBr and its similarly stable relative IMesBr demonstrates metal complex specific changes in NHC donicity versus the ubiquitous IPr and IMes. Application to a Suzuki coupling and an iridium transfer hydrogenation gives superior outcomes using IPrBr and IMesBr.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 1 شماره
صفحات -
تاریخ انتشار 2015